Tolmachiov A. M., Trubnikov O. I., Godovikov I. A., Kuznetsova T. A.
Adsorption
databank. Physico-Chemical Characteristics of Vapor Adsorption on Zeolites
Abstract
Different
variants of experimental data processing of vapor adsorption on zeolites are
analyzed in connection of creation of adsorption databank. It is shown that the
most complete and reliable characteristics of adsorption systems could be
obtained with combination of Dubinin-Astachov equation with the equation system
ensuing from the Ono-Kondo model and stoichiometric and osmotic theories with
corresponding assumptions about concentration dependence of adsorbat activity
coefficients. The obtained parameters
are recommended to be included in adsorption databank in addition to initial
experimental information.
Copyright (C) Chemistry Dept., Moscow State University, 2002
|
|