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Pergushov V. D.

Radicals Grafted to Activated Surface of Silicon Dioxide: Magnetic Parameters, Structure, and Chemical

Abstract

The structure and molecular dynamics of grafted on activated silica surface radicals ºSiOC·X2 (X=H, D, F ; X2=O) and nitroxide ºSiON(O·)CX3 (X=H, D) were investigated. Magnetic and dynamic characteristics of grafted radicals were determined and the barriers of fragment radicals rotation around different bonds were estimated.
Moscow University Chemistry Bulletin.
2002, Vol. 43, No. 5, P. 259 		   
Copyright (C) Chemistry Dept., Moscow State University, 2002
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