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M. A. Proskurnin, M. Yu. Kononets, V. V. Chernysh
Correlations
of the Conplexes Stability Constants Determined by Thermal Lensing
Abstract
Correlation relationships of
stability constants for complexes of iron(II) and copper(I) with
1,10-phenanthroline, copper(II) with 2,9-dimethyl-1,10-phenanthroline, and
bismuth(III) with iodide ions are considered. The compared data were found
experimentally at the level of nґ 10–8 – nґ 10–6 M by thermal lensing, previously found by for other
methods and calculated from the theoretical (statistical) approach. The
considered correlations show that the stability constants found by thermal
lensing are determined with high accuracy.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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