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A . V. Rogov, S. P. Mikhalev, A. A. Granovsky, V. N. Soloviev, A. V. Nemukhin, G. B. Sergeev
Experimental and theoretical study of the interaction
between magnesium particles and carbon tetrachloride
Abstract
Reactions
of polyhalidemethanes (CCl4, CHCl3, CFCl3) with magnesium
particles were investigated in low temperature cocondensates. Experimentally
obtained absorption bands are in a good agreement with the quantum chemical
data. The possible mechanism of the reaction was suggested based on ab initio
quantum chemical calculations for magnesium particles with carbon
tetrachloride.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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