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N. S. Dubinina, E. K. Beloglazkina, N. V. Zyk
Cyclohexene chlorosulfenilation: nucleofilic substitution of halogen for
amino- and mercapto-groups. an investigation of obtained aminosulfides and
mercaptosulfides in complex formation reactions
Abstract
(2-aminocycIohexyl)phenylsulfide,(2-mercaptocyclohexyl)phenylsulfide, 2,2'-biaminobicyclohexylsulfide and
2,2'-bimercaptobicyclohexyIsulfide were
synthesed from the base of (2-chlorcyclohexyl)phenyIsulfide and
2,2'-bichlorbicyclohexylsuIfide by Gabrial reactions and action of thiourea.
The possibility of transition metal complex formation (Ni(II), Co(II),
Cu(II),Fe(III)) are investigated.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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