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A. L. Voskov, I. A. Uspenskaya

Calculation of phase diagrams of the Ln – Ba (Ln – Gd, Pr, Nd, Sm) systems

Abstract

On the base of published data of thermodynamic properties and phase equilibria in rare earth metal – barium systems a thermodynamic model of liquid was suggested. Phase diagrams of the Ln–Ba (Ln=Gd, Pr, Nd, Sm) systems were calculated. The interaction parameter of Gd1–xBax “regular” melt was estimated in assumption of proportionality between energies of liquid Ln and Ba interparticle interactions and rare earth element radii.
Moscow University Chemistry Bulletin.
2008, Vol. 49, No. 5, P. 295
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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