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I. V. Barinov, V. A. Chertkov

13C and NMR spectra of the coordinated propargylic cations [Cp2Mo2(CO)4(m-h2,h3-(HCºCCR1R2)]+ BF4-

Abstract

The deshielding effect of (C+) is observed in 13C spectra of coordinated propargylic cations [Cp2Mo2(CO)4(m-h2, h3-( HCºCCR1R2)]+ BF4- (R1=R2 = H) 1, (R1= Me, R2 = H) 2, (R1=R2 =Me) 3; the effect is increased with growing of Mo-C+ distance.
Moscow University Chemistry Bulletin.
2009, Vol. 50, No. 1, P. 29 		   
Copyright (C) Chemistry Dept., Moscow State University, 2002
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