1986, Bowers and Weitekamp | First discovery, which showed the ability of this NMR–technique to clucidate the pairwise hydrogen transfer to the substrates. |
1988-94, Bargon, Eisenberg et al. | Identification of unstable dihydride intermediates, participating in the catalytic cycles of hydrogenation reactions catalyzed by rhodium, iridium, palladium and ruthenium complexes of different structures. |
1995-96, Bargon, Klages, Permin, Petrosyan | Study of PHIP in the homogeneous hydrogenation reactions of alkenes and alkynes, catalyzed by various platinum complexes. |
Inorganic complexes:
Cl2Pt(PPH3)2, Cl(H)Pt(PPh3)2, Cl(H)Pt(PMePh2)2, Cl3Sn(H)Pt(PR3)2 [R=Ph, Me]
Organometallic complexes: