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S. Yu. Lanskaya, A. V. Bashilov, Yu. A. Zolotov
Investigation of Kinetics
of Ruthenium(IV) Complexation with Nitroso P Salt under Microwave Irradiation. Comparison
with Classical Heating
Abstract
The kinetics of
complexation in the system ruthenium(IV) – Nitroso R Salt under classical
heating (60–98°C) and under microwave irradiation (60–160°C) was studied. Rate
constants, activation energies, and ratio of components were evaluated. It was
pointed that the pre-exponential coefficient in Arrhenius’s equation is
influenced by nonthermal effect of microwave irradiation.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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