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N. Ye. Shchepina, V. V. Avrorin, G. A. Badun, S. B. Lewis, V. M. Fedoseev, S. Ye. Ukhanov
Reaction of Direct Phenylation by Nucleogenic Cations
as a Method of Synthesis of Unknown or Complicated Compounds Labeled with
Tritium
Abstract
As
a result of ion-molecular reactions of nucleogenic phenyl cations, generated by
tritium b-decay in polytritiated benzene, with nucleophilic
centers of investigated substrates the direct phenylation has been realized and
unknown tritium labeled aromatic derivatives of polyvalent fluorine together
with the different N-phenyl substituted pyridinium compounds which are
important syntones for biological and medical investigations have been
synthesized.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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