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O. T. Kasaikina, A. A. Golyavin, D. A. Krugovov, Z. S. Kartasheva, L. M. Pisarenko

Micellar catalysis in the lipid oxidation

Abstract

Catalytic effects of surfactants (S) on the lipid and hydrocarbon oxidation have been discussed. Hydroperoxides (ROOH), the primary amphiphilic products of lipid oxidation by molecular oxygen, were shown to form mixed micelles {nROOH..mS} together with known cationic surfactants, in which the accelerated decomposition of ROOH occurs; other polar components namely metal compounds, inhibitors etc. can be concentrated in mixed micelles as well, what affects significantly the oxidation rate and mechanism.
Moscow University Chemistry Bulletin.
2010, Vol. 51, No. 3, P. 246
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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